Rayon care/alternatives?

I’ve got some rayon shirts from Express that I really like. They’re soft, breathable, and the way drape is super comfortable. However, that shit wrinkles when you look at it the wrong way.

I live in satan’s armpit AKA the southeastern USA, where the sauna of an atmosphere makes this even worse.

Do you guys have any special methods for washing or wrinkle-proofing your rayon? Alternatively, do you recommend any other materials that are comfortable, not stiff, and good for muggy weather?
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