Alias'ing an MS exchange email address

Sorry if this is a simple question, but I'm always wary/shit-scared of messing with emails/dns 😄
I'm using a primary domain on O365, exampleA.com, with licenses and users set up, and have another unrelated domain, exampleB.com, with no licenses.

I'd like to alias me@exampleA.com, with me@exampleB.com, so that anyone emailing @exampleB.com will actually mail @exampleA.com.

I've found an MS guide here: https://learn.microsoft.com/en-us/microsoft-365/admin/setup/add-domain?view=o365-worldwide

but just wanted to ask "is this doing what I think it's doing", and if any replies would appear as being from exampleB.com or if it will default to exampleA.com?

Thanks!
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