rxn mechanism

R-OH + PX₃ → R-X + H₃PO₃ can someone give the reaction mechanism for this
15 Replies
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@Dexter
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Opt
Opt2mo ago
Chemistry LibreTexts
10.2: Reactions with Phosphorus Halides
Because of the limited synthetic utility of reacting alcohols with hydrohalic acids to form alkyl halides, the alternative reagents thionyl chloride and phosphorous tribromide. have been developed.
Opt
Opt2mo ago
No description
Sephrina
SephrinaOP2mo ago
but yaha to first tak hai main mujhe ye smaj nhi ara ki h2po3 kaise ayega you got any idea? @Opt
Opt
Opt2mo ago
You see that HOP(OR)2? Replace OR with OH. H3PO3 Voila Basically, two more iterations of attacking with H(+), Br(-)
Sephrina
SephrinaOP2mo ago
hn but structure wise dekhe to aise karne pe p would be attached to 3 oh group and iska jo structure hai it has 1 O double bond 2 oh group and 1 H attached to P
Opt
Opt2mo ago
The double bond is there. See? It's an ester
Sephrina
SephrinaOP2mo ago
mujhe abhi bhi smaj nhi aya
Sephrina
SephrinaOP2mo ago
iska hisab se maine 1st step kiya
No description
Sephrina
SephrinaOP2mo ago
to product aya HOPX2
Opt
Opt2mo ago
No description
Opt
Opt2mo ago
Tautomerism exists. P(OH)3 tautomerises to the usual form we know
Sephrina
SephrinaOP2mo ago
OHHHH ok then ye wala fact nhi pata tha 😅 +solved @Opt
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