oc2

in i. ArSn takes place and cl is replaced by oh cant figure out ahead
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29 Replies
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CorrodedCoffin
CorrodedCoffinOP4mo ago
i was thinking along the lines of benzyne mechanism cuz ArSn is not possible due to ERG on ortho and no EWG on para however that doesnt give the req product
Sephrina
Sephrina4mo ago
is this from aakash module?
CorrodedCoffin
CorrodedCoffinOP4mo ago
yep
Sephrina
Sephrina4mo ago
haha yeah i have solved it let me look wait
CorrodedCoffin
CorrodedCoffinOP4mo ago
alrr
Sephrina
Sephrina4mo ago
can you tell the que no?
CorrodedCoffin
CorrodedCoffinOP4mo ago
assignment ques 6
Sephrina
Sephrina4mo ago
set 1?
CorrodedCoffin
CorrodedCoffinOP4mo ago
huh its in aakash invictus module not the normal one just solve the ques bruh
Sephrina
Sephrina4mo ago
the koh will attack on most reactive halogen which removes br group adding oh group and then the naoh and ch3 cl together remove h from oh and the ch3 gets added to o giving in end 2 chloro 1 methoxy 4 nitrobenzene typing is hard bro
CorrodedCoffin
CorrodedCoffinOP4mo ago
2 bromo but yes
Sephrina
Sephrina4mo ago
why 2 bromo?
CorrodedCoffin
CorrodedCoffinOP4mo ago
because cl will be removed arsn but why is naoh + chcl3 reacting with -oh
Sephrina
Sephrina4mo ago
naoh strong base so it removes h and its ch3cl so cl gets removed and the ch3 attaches to o
CorrodedCoffin
CorrodedCoffinOP4mo ago
in the second rxn , benzyne mechanism kyu nahi hua your process makes sense to me why do we have to proceed that way
Weirdo
Weirdo4mo ago
??? Shine some light on your statement
Sephrina
Sephrina4mo ago
try to read up more from ncert you will understand this much better on how the strong base substitution works
CorrodedCoffin
CorrodedCoffinOP4mo ago
Why can't this work
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Sephrina
Sephrina4mo ago
i think u should first read up on ncert then it make sense more
CorrodedCoffin
CorrodedCoffinOP4mo ago
ohh ig acid base is prefered over benzyne
Opt
Opt4mo ago
No, see, you're abstracting a proton in both cases, but the OH proton is much easier to pull away than one which is connected to benzene ring.
CorrodedCoffin
CorrodedCoffinOP4mo ago
due to steric reasons?
Opt
Opt4mo ago
Active vs. inactive hydrogen. Phenate has resonance stability, but lp on the benzene carbon isn't involved in resonance.
CorrodedCoffin
CorrodedCoffinOP4mo ago
so its all about finding the most stable anion when doing reactions with naoh
Opt
Opt4mo ago
Pretty much always, really, assuming you aren't looking for a kinetic product of a reaction with multiple pathways
CorrodedCoffin
CorrodedCoffinOP4mo ago
alr got it thanx +solved @Opt @Sephrina
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