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@Dexter
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+solved @user1 @user2... to close the thread when your doubt is solved. Mention the users who helped you solve the doubt. This will be added to their stats.@Enamine remember this question
the answer key ....
Whatttt
Ohhhhh
I guess we did some shit that we shouldn't have
ðŸ˜
Isiliye draw karke better hota hai
ab to mai isme aur confuse ho gyi hu
Ruko what?
It has formed the 3 membered nitrogen vaali ring
Ohkay
But usse alkaline hydrolysis ka rate badh kaise gaya?
Ahmm aight I see
Oii @Sephrina you here right?
yss
was posting another
Yeah so dekho
The thing is
That first attack
From nitrogen to kick out chlorine
That's intramolecular right?
It would happen regardless if there is a base or not
wait but why
Or whatever.... A nucleophile
'cause we have a lone pair on the nitrogen
A leaving group on just one carbon apart
to cl ki electronegativity usko le legi the extra lone pair?
Yeah 3 membered rings are unstable agreed
That's why the molecule is shown to be in the open form
mtlab to irl me ye molecule in 2 state me juggle karega?
form sorry
not state
Cl is acting as a mere leaving group
Uska size and electronegativity both allow it to be a good leaving group
Feel like there is an equilibrium between the two
The open form and the 3 membered ring form
'cause it's too strained
hn to mtlab uska electron wanting factor will take that extra e right?
The reaction would come back too
3 membered yh very much
Yeah making a Cl- is favourable
So basically there is this equilibrium
Jisme dono forms hain
uh huh okk
So half of it is say open
Half of it is that 3 membered ring
Jabki carbon ke case me
It's just the open
hn
Now....
Where we went wrong was
Ki agar nitrogen ki ring ban gayi
To hydrolysis would be inhibited
Jabki actually it would be favoured
why though
We said ki alkaline hydrolysis matlab Cl ko nikaal ke OH ka lagna
Jabki more precisely
It's actually OH- ka attack
hn
That's alkaline hydrolysis
Ab usme OH- ko attack karne ke liye more reactive species kiske case me mil rahi hai?
uh ye sn1 lega?
SN2
without n?
Primary Carbon strong nucleophile
N vaale case me kya hai?
3 membered ring!
Carbon vaale case me kya hai
oh hnn
Bas open form
hn
Open form is common to both
So not much of a difference
But ring vaali more reactive form bas nitrogen ke paas hai
To uska hydrolysis jaldi hoga
Sorry mai tab neend me tha jab last time bataya
ring wali more reactive hogi?
Just realised this
Ring is strained right?
koi nhi koi nhi
Open chain isn't
I'll summarise all of this to you
Draw karke bhejta
hnn
hnn
Bruh ye boxes kahan gaye lmao
Doesn’t matter anyways chalo
+solved @Enamine
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