Kinetics

Bro istg these question are so weird For the 2nd we neet to determine the rate law
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59 Replies
iTeachChem Helper
@Dexter
iTeachChem Helper
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Real potato
Real potato2mo ago
Are data dia hua hai usse rate of rxn find kro
Sephrina
Sephrina2mo ago
neet?
Real potato
Real potato2mo ago
Fir 2-3 alag data ka use krke rate law likho jisme conc ki power kuch x and y assume kro equations ko divide krke Rate constant kat jayega or order pata chal jayega Fir rate law likh paoge I think he means need
Sephrina
Sephrina2mo ago
2 bas se nhi kar sakte? us se bhi ho jayega
Real potato
Real potato2mo ago
Ha wo data p depend krta hai
Sephrina
Sephrina2mo ago
ik yaar mera joke mat khrb karo
Real potato
Real potato2mo ago
Sometime we need to solve 3 jab data har concentration ka alag hota hai to cancel out ni hota hai
Sephrina
Sephrina2mo ago
oh well hn tab
flower
flowerOP2mo ago
Nahi ho raha naa Thing is dono me initial compositions is diffrent For both cases Usme kaise karoge ye Ye nahi hoga idhar We need to use both to find k Both cases
Real potato
Real potato2mo ago
3 data dia hai na 3 equation bana k try kro
flower
flowerOP2mo ago
Aayein
iTeachChem
iTeachChem2mo ago
Send actual q. Pic hai?
flower
flowerOP2mo ago
nahi sir ne class me example karwaye the ye 3 equation mai kar bhi lunga to merko har case ka ek alag k aaega @Real potato ill send in a cleaner write up of the question
flower
flowerOP2mo ago
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flower
flowerOP2mo ago
,rotate
TeXit
TeXit2mo ago
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SirLancelotDuLac
Assuming the time is in minutes: Note that A and b are getting depleted by the same values, hence there is an excess of A in the reaction. Further note that the ratio of consecutive values of [B] are in the ratio of 0.8, which is a characteristic for first order reaction in B. Furthermore, let there be two consecutive concentrations of B as $B{0}e^{kt}$ and $B{0}e^{k(t+10)}$ then their ratio is $e^{-k \cdot 10}$ which is equal to 0.8
TeXit
TeXit2mo ago
SirLancelotDuLac
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SirLancelotDuLac
Take log both sides then and solve.
flower
flowerOP2mo ago
A and b are getting depleted by the same values, wdym same values
SirLancelotDuLac
Looking at the first 2, both [A] and [B] are depleted by .002, then by .0016 and so on. Meaning when [B] tends to zero, [A] tends to A-[B]=0.01 This tells us about the stoichiometric coefficient, which I just thought of writing.
flower
flowerOP2mo ago
ohhh waisee okok fine ok ig this makes a lot of sense what about the second one
flower
flowerOP2mo ago
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SirLancelotDuLac
The first and second columns indicate initial concentration or concc. at that time?
flower
flowerOP2mo ago
initial @SirLancelotDuLac hapl @Real potato hapl
Real potato
Real potato2mo ago
bhai initial conc or time t for conc dia hai usse aap rate of rxn nikalo Fir rate = K [A]^x [B]^y Given data se 3 eqn ban jayega Compare krke x or Y ki value aajyegi by dividing equations rate constant cancle out ho jayega A or B k respect me order aagya fir rate of rate law expression likh paaoge
SirLancelotDuLac
Okie, bear with me on this but, from the first one, ii.) On having dichromate, the reaction takes twice as long to be half completed iii.) On halving the HgCl_2, the reaction is nearly half completed at the same time. Yeah nvm this doesn't give much lmao.
flower
flowerOP2mo ago
Bhai AB wala ho gaya Hg wala hapl kar do
Real potato
Real potato2mo ago
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Real potato
Real potato2mo ago
Ig esehi ho payega equation ko divide krke m or n nikal lena @Phalawor
flower
flowerOP2mo ago
HAWW ITNI MEHNAT BRUHHHHHHH
Real potato
Real potato2mo ago
nah easy h dekho na first or second eqn me ek ek bracket to pura cancle ho ra hai
SirLancelotDuLac
They are different reactions though? For instance the amount of dichromate is same in 3 and 1 which isn't possible. It can't be the same reaction.
Real potato
Real potato2mo ago
Teeno me jo time dia hai wo zero se hi hai na?
SirLancelotDuLac
But initial conditions alag hai teeno mein.
Real potato
Real potato2mo ago
But isse rate constant thodi effect hoga
SirLancelotDuLac
But equations mein rate kaise likhenge, jabh same reaction ke do instances ki information hi nahi hai?
Real potato
Real potato2mo ago
Hg2cl2 ka dia hai to avg rate to likh skte hai na? C2-C1/T?
SirLancelotDuLac
But agar teeno alag alag reactions hai, toh how will we get c2 for, say reaction 3? Because teeno reaction ki initial conditions alag hai Oh, I get your point. Do we have to write the reaction out?
Real potato
Real potato2mo ago
But order to same ana cheye na reacatants k respect me?
flower
flowerOP2mo ago
npoe no reaction given and acc to my teach its not needed either
Real potato
Real potato2mo ago
Do you know the ans?
flower
flowerOP2mo ago
nope i asked him today he said later so idk maybe tommrow
Real potato
Real potato2mo ago
Ye standard questions hai so what im trying to do is solve thru standard method like by finding the order first but yeah i may be wrong though i havent revised kinetics in a while
SirLancelotDuLac
Ye, but we don't know c2 in c2-c1 na?
flower
flowerOP2mo ago
nope ye wo wala simple table question nahi hai
SirLancelotDuLac
Depression x 1,000
flower
flowerOP2mo ago
IKRR
Real potato
Real potato2mo ago
Last me jo hg2cl2 wla hai wo dia to hai?
flower
flowerOP2mo ago
HES GIVING OUT SOME REAL FIRE QUESTIONS
Real potato
Real potato2mo ago
I mean mast wala table
SirLancelotDuLac
Ye, so to get final concentrations, we need to write out the reaction no?
Real potato
Real potato2mo ago
Final concentration to kisi ek ka hi cheye padta hai avg rate likhne baki ka nikal kar kya krege? hg2cl2 se hi avg rate aajyegi :Saul_Goodman:
SirLancelotDuLac
Fair point.
Real potato
Real potato2mo ago
@Phalawor please confirm this once you get to know the proper method and ans
flower
flowerOP2mo ago
haa yaar kal puchta hu or else ill go mad
Sephrina
Sephrina2mo ago
mai ye question save kar leti jab kinetics kar lungi tab karungi

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