17 Replies
@Dexter
Note for OP
+solved @user1 @user2... to close the thread when your doubt is solved. Mention the users who helped you solve the doubt. This will be added to their stats.Yes, it's correct
1,2,4,5,7,9 have lone pair
So, can participate in resonance
ah okay
yeah i just wanted to confirm
thanks a bunch
we only look at the atom directly attached na.. like even if there's a withdrawing grp after it we wont look at it like nhcoch3
Yeah
It's like cross conjugation
It will still show +M effect although uska intensity kam ho jayega kyuki like in this case Nhcoch3 nitrogen ka lone pair resonance krne lgega Carbon ke oxygen k sath
right, got it.. and +M bw OH and OCH3 how do i compare
OCH3 mei CH3 ka +I lagega to oxygen ki electron density badh jaegi to vo zyada +M show karega as compared to OH
Ahmm actually this is wrong
OCH3 has a larger bond angles
Because of steric repulsion of the CH3 by the rest of the carbon chain
This increases %s character in the oxygen in the OCH3
Which increases its electronegativity (Bent's Rule)
Because of this, it doesn't donate as much as OH
Do you guys get this? @Prachi @ns @Real potato
yeah.. cuz i solved a problem where oh was considered to have more +m
thanks so much
also cl ka toh -i dominate karta hai na
Yep, forgot about the repulsion factor
Actually the problem is that alkyls are actually not +I groups
So I kinda refrain from using that in my explanation 🙂
(it's been proved recently)
#💁│general
yup i understood ur point about bents rule
..?
welp cant wait to have that added into NCERT 8 years from now :DD
yeah. like it shows both +M and -I but we consider -i