Haloalkanes

how do i interpret this properly?
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4 Replies
iTeachChem Helper
@Dexter
iTeachChem Helper
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flower
flowerOP6d ago
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Varun_Arora
Varun_Arora2d ago
Analyse the situation by all the data you already have first before making a prediction So first you see A primary halide A very high possibility that it will go an SN2 Reaction Okay We read further Ethanol A weak nucleophile Then we see EtONa Which is a strong enough base and good nucleophile Now we also see one more thing EtSNa Now S based nucleophiles would be relatively less reactive or nucleophilic Why? Stability of negative on sulphur because of that extra shell that gets added So the sulphur one is out of question (for being the major choice) Now we have 2 options Either a substitution or an elimination But as it’s primary halide, less steric hindrance in the SN2 transition state This leads to the substitution product being major Aaah I missed one thing Substitution by what? OH or OEt? Now you gotta see which of these is more nucleophilic

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