hydrocarbons

arrange the following compounds in correct order of rate of decarboxylation methanoic acid ethanoic propanoic benzoic
12 Replies
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CorrodedCoffin
CorrodedCoffinOP7mo ago
from my understanding we have to compare stability of carbanion benzoic acid > metha>eth>prop hona chahiye then but given ans is benzoic>eth>prop>meth
Opt
Opt7mo ago
Methanoic acid doesn't have a carbanion. It can't decarboxylate at all, it can only be oxidised. It's formic acid na?
CorrodedCoffin
CorrodedCoffinOP7mo ago
yepp how to compare then
Opt
Opt7mo ago
You got the rest right It's just that formic acid can't be decarboxylated at all
CorrodedCoffin
CorrodedCoffinOP7mo ago
so its automatically at the end ? what bout this tho
Opt
Opt7mo ago
Yes
CorrodedCoffin
CorrodedCoffinOP7mo ago
given ans is wrong then ?
Opt
Opt7mo ago
Given is correct Benzoic because resonance stability, then acetic and propanoic based on chain length, then formic because it cannot be decarboxylated in the first place.
CorrodedCoffin
CorrodedCoffinOP7mo ago
alr got it +solved @Opt
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